Issue 12, 1973
From the journal:

Journal of the Chemical Society, Dalton Transactions

Alkyl and aryl migration from carbon monoxide to platinum promoted by silver ion

Mitsuru Kubota,   Richard K. Rothrock  and  J. Geibel  

Abstract

Abstraction of chloride with AgPF6 from Pt(PPh3)2Cl(RCO)(R = Me, Ph, p-MeC6H4, p-MeOC6H4, or p-O2NC6H4) in ethanol leads to migration of R from carbon monoxide to platinum to form cationic platinum carbonyl complexes, [Pt(PPh3)2(CO)R]+. Silver ion abstraction of chloride from Pt(PPh3)2Cl(RCO) in acetonitrile leads to isolation of [Pt(PPh3)2(RCO)(MeCN)]+. Migration of R was not observed for these nitrile solvated complexes, but was observed in similar acetone solvated complexes.

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Article information

DOI
https://doi.org/10.1039/DT9730001267
Article type
Paper

J. Chem. Soc., Dalton Trans., 1973, 1267-1269

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Alkyl and aryl migration from carbon monoxide to platinum promoted by silver ion

M. Kubota, R. K. Rothrock and J. Geibel, J. Chem. Soc., Dalton Trans., 1973, 1267 DOI: 10.1039/DT9730001267

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