A technique which eliminates effects of changes in asymmetry potential has been adapted for use in pH titrations with high-resistance glass electrodes. A study, using cells without liquid junctions, has been made of the hydrolysis of the oxovanadium(IV) ion and of its complexes with the 1,2-dihydroxybenzenato(2–) ion. Equilibrium constants are reported.
R. P. Henry, P. C. H. Mitchell and J. E. Prue, J. Chem. Soc., Dalton Trans., 1973, 1156 DOI: 10.1039/DT9730001156
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