The preparations of [OsH4L3](L = tertiary phosphine or arsine) are described. Many neutral ligands L′(but not dinitrogen) will displace dihydrogen yielding complexes cis-[OsH2L3L′]. The hydrido-complexes are Lewis bases. They are also catalysts for olefin isomerisation and polymerization.
B. Bell, J. Chatt and G. J. Leigh, J. Chem. Soc., Dalton Trans., 1973, 997 DOI: 10.1039/DT9730000997
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