The title ions have been prepared as tetra-alkylammonium salts and their i.r. and Raman spectra are reported and assigned according to D3d symmetry. Normal-co-ordinate calculations have been made for Ga2Cl62– which indicate a Ga–Ga force constant of 217 N m–1.
C. A. Evans, K. H. Tan, S. P. Tapper and M. J. Taylor, J. Chem. Soc., Dalton Trans., 1973, 988 DOI: 10.1039/DT9730000988
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