Protonation of solutions containing the anions [MnX(COMe)(CO)4]–(X = Br or I) affords the stable crystalline hydroxycarbene complexes cis-[MnX{C(OH)Me}(CO)4], characterised by i.r., n.m.r., and mass spectroscopy. Reaction with water yields methyl(pentacarbonyl)manganese, whereas, cyclohexylamine gives acetyl(cyclo-hexylamine) tetracarbonylmanganese.
J. R. Moss, M. Green and F. G. A. Stone, J. Chem. Soc., Dalton Trans., 1973, 975 DOI: 10.1039/DT9730000975
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