Issue 9, 1973
From the journal:

Journal of the Chemical Society, Dalton Transactions

Electron spin resonance studies of γ-irradiated hexacyanoruthenate(II) ions in various host lattices

Martyn C. R. Symons  and  James G. Wilkinson  

Abstract

E.s.r. data for γ-irradiated hexacyanoruthenate(II) ions doped into various host lattices are reported. The main complexes formed are RuI species (low-spin d7), assigned as Ru(CN)4(CN′)H2O4– Ru(CN)4(CN′)25–, Ru(CN)4(CN′)Hal5–, and Ru(CN)4(Hal)25–, where CN′ indicates a cyanide ligand tilted off the z-axis. The magnitudes of the hyperfine coupling to ruthenium and nitrogen are used to discuss the structures of the complexes.

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Article information

DOI
https://doi.org/10.1039/DT9730000965
Article type
Paper

J. Chem. Soc., Dalton Trans., 1973, 965-969

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Electron spin resonance studies of γ-irradiated hexacyanoruthenate(II) ions in various host lattices

M. C. R. Symons and J. G. Wilkinson, J. Chem. Soc., Dalton Trans., 1973, 965 DOI: 10.1039/DT9730000965

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