Issue 9, 1973
From the journal:

Journal of the Chemical Society, Dalton Transactions

Interaction of hydridocarbonyltris(triphenylphosphine) complexes of iridium(I) and rhodium(I) with organic acids

Charles K. Brown,   Denis Georgiou  and  Geoffrey Wilkinson  

Abstract

The interaction of the complexes MH(CO)(PPh3)3[M = Rh or Ir] with organic acids such as p-nitrophenol, pyridine-2-thiol, trifluoroacetic, and trifluoromethylsulphonic acids have been studied. The new complexes Ir(OC6H4NO2)(CO)(PPh3)2, Ir(CF3CO2)(CO)(PPh3)2, [IrH2(CO)(PPh3)3)]CF3SO3, and IrH(C6H4NS)(PPh3)2 have been prepared; the latter complex has been found to insert ethylene to form the alkyl complex Ir(C2H5)-(C6H4NS)2(PPh3)2. More convenient routes to Rh(CF3CO2)(CO)(PPh3)2, IrH(CF3CO2)2(CO)(PPh3)2, and the cationic complex [Rh(CO)(PPh3)3]+ are given.

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Article information

DOI
https://doi.org/10.1039/DT9730000929
Article type
Paper

J. Chem. Soc., Dalton Trans., 1973, 929-933

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Interaction of hydridocarbonyltris(triphenylphosphine) complexes of iridium(I) and rhodium(I) with organic acids

C. K. Brown, D. Georgiou and G. Wilkinson, J. Chem. Soc., Dalton Trans., 1973, 929 DOI: 10.1039/DT9730000929

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