The preparation and properties of vinyltitanium trichloride and its adducts with tetrahydrofuran and 1,2-dimethoxyethane are described. The nature of the vinyl–titanium bond and the mechanism of decomposition of vinyltitanium trichloride are discussed.
B. J. Hewitt, A. K. Holliday and R. J. Puddephatt, J. Chem. Soc., Dalton Trans., 1973, 801 DOI: 10.1039/DT9730000801
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