Tris(quinolin-8-olato)titanium(III) has been prepared by reaction of α-titanium trichloride and quinolin-8-ol in acetonitrile. Magnetic-susceptibility measurements, e.s.r. and electronic absorption spectra, and X-ray powder diffraction studies indicate that the complex is a distorted octahedral monomer with an orbitally non-degenerate ground state.
F. B. Taylor and T. A. Wilkins, J. Chem. Soc., Dalton Trans., 1973, 87 DOI: 10.1039/DT9730000087
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