Liquid ammonia solutions of simple metal salts give good Raman spectra with little interference from solvent bands; the metal–nitrogen stretching vibrations indicate unusual co-ordination numbers with Zn2+, Hg2+, and Ag+, and ion-association effects are smaller than in aqueous solutions.
P. Gans and J. B. Gill, J. Chem. Soc., Chem. Commun., 1973, 914b DOI: 10.1039/C3973000914B
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