Kinetic studies provide support for benzonitrile sulphide as an intermediate produced in the decarboxylation of 5-phenyl-1,3,4-oxathiazol-2-one; thermolysis of 5-methyl-1,3,4-oxathiazol-2-one in the presence of dimethyl acetylenedicarboxylate produced dimethyl 3-methylisothiazole-4,5-dicarboxylate, presumably via acetonitrile sulphide.
R. K. Howe and J. E. Franz, J. Chem. Soc., Chem. Commun., 1973, 524b DOI: 10.1039/C3973000524B
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