Methyl isonitrile inserts into the metal-chlorine bond of niobium and tantalum pentachlorides to give [MCI4{C(CI)![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
NMe}(MeNC)](M = Nb or Ta) and [NbCI3{C(CI)NMe}2(CNMe)]; the complex [NbCI3{C-(CI)NMe}2PPh3] has also been prepared.
B. Crociani and R. L. Richards, J. Chem. Soc., Chem. Commun., 1973, 127b DOI: 10.1039/C3973000127B
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