Issue 24, 1973
From the journal:

Journal of the Chemical Society, Chemical Communications

Free radicals as intermediates in the oxidative addition of alkyl halides to platinum(0)

Michael F. Lappert  and  Peter W. Lednor  

Abstract

Free radicals are implicated in the oxidative addition of an alkyl halide RX (MeI, CD3I, EtI, or PhCH2Br) to Pt(PPh3)3, as shown by identifying (e.s.r.) the derived nitroxide But(R)NO. using ButNO as a spin trap; a non-chain mechanism is proposed, with the formation of [PtIX(PPh3)2]· as rate limiting.

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Article information

DOI
https://doi.org/10.1039/C39730000948
Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 948-949

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Free radicals as intermediates in the oxidative addition of alkyl halides to platinum(0)

M. F. Lappert and P. W. Lednor, J. Chem. Soc., Chem. Commun., 1973, 948 DOI: 10.1039/C39730000948

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