Issue 24, 1973

Facilitation of intramolecular 1,2-shifts in radicals by protonation, and the mechanism of reactions catalysed by 5′-deoxyadenosylcobalamin

Abstract

Ab initio molecular orbital calculations show that 1,2-intramolecular shifts in simple organic radicals may be facilitated by protonation of the migrating group; the relevance of this result to reactions catalysed by 5′-deoxyadenosylcobalamin is demonstrated.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 939-941

Facilitation of intramolecular 1,2-shifts in radicals by protonation, and the mechanism of reactions catalysed by 5′-deoxyadenosylcobalamin

B. T. Golding and L. Radom, J. Chem. Soc., Chem. Commun., 1973, 939 DOI: 10.1039/C39730000939

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements