Issue 24, 1973

Nature of the intermediate in the Cornforth rearrangement

Abstract

The thermal rearrangement of 4-carbonyl substituted oxazoles gave a negative value for the reaction constant ρ, and correlated with enhanced σ values (σ+); a small rate increase was observed upon running the reaction in solvents of increasing dielectric constant.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 925-926

Nature of the intermediate in the Cornforth rearrangement

M. J. S. Dewar, P. A. Spanninger and I. J. Turchi, J. Chem. Soc., Chem. Commun., 1973, 925 DOI: 10.1039/C39730000925

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