Issue 23, 1973

Separation and unusual stability of the sulphur-bridged ion Mo2S2O22+

Abstract

The sulphur-bridged ion, Mo2S2O22+, which has been separated from the parent compound, Na2Mo2O2S2-(cysteine)2, is stable towards acids and does not dissociate to a paramagnetic monomeric species, as does its oxo-bridged analogue, Mo2O42+, even in very concentrated acidic solutions.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 909-910

Separation and unusual stability of the sulphur-bridged ion Mo2S2O22+

B. Spivack and Z. Dori, J. Chem. Soc., Chem. Commun., 1973, 909 DOI: 10.1039/C39730000909

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