The reversible formation of a nitric oxide adduct with tetraphenylporphyriniron(III) chloride formulated as [FeII(TPP)Cl–NO+] is observed in toluene, but reductive nitrosylation to give FeII(TPP)·NO occurs in the presence of a hydroxylic solvent, in reactions analogous to hemeprotein interactions with nitric oxide.
B. B. Wayland and L. W. Olson, J. Chem. Soc., Chem. Commun., 1973, 897 DOI: 10.1039/C39730000897
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