Phenacyl bromide and its derivatives in the presence of zinc undergo coupling reactions to 1,4-diketones; free radicals, detected and identified by e.s.r. in the above reactions, also undergo anti-Markownikov additions with terminal olefins.
E. Ghera, D. H. Perry and S. Shoua, J. Chem. Soc., Chem. Commun., 1973, 858 DOI: 10.1039/C39730000858
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