The addition of Na+C5H5– and FeCl2 to (C5H5)-CoIII(C2B7H9) previously reduced with sodium naphthalide formed the heterobimetallocarborane, (C5H5)CoIII(C2B7H9)FeIII(C5H5); a larger homologue of this cobaltaferracarborane, (C5H5)CoIII(C2B9H11)FeIII(C5H5, was prepared by the reaction of C5H5)CoIII(C2B10H12) with ethanolic potassium hydroxide in the presence of FeCl2 and C5H6.
D. F. Dustin, W. J. Evans and M. F. Hawthorne, J. Chem. Soc., Chem. Commun., 1973, 805 DOI: 10.1039/C39730000805
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