Issue 18, 1973

Equilibration of biadamantane isomers

Abstract

In agreement with molecular mechanics calculations, 2,2′-biadamantane (2) is more stable than 1,1′-biadamantane (1): (1)⇌(2), ΔGIo(298)=–0·51 ± 0·21 kcal mol–1, ΔHIo= 1·11 ± 0·12 kcal mol–1, and ΔSIo= 5·4 ± 0·3 cal deg–1 mol–1.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 685-686

Equilibration of biadamantane isomers

J. Slutsky, E. M. Engler and P. v. R. Schleyer, J. Chem. Soc., Chem. Commun., 1973, 685 DOI: 10.1039/C39730000685

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