Irradiation of the 520 nm d-d absorption band of Co(NH3)5N32+ has been found to result in relatively high (ϕ≃ 0·2) yields of ammonia aquation with no other primary photoprocess detectable; this contrasts to what is commonly considered to be the general pattern of cobalt(III) photochemistry.
G. Ferraudi and J. F. Endicott, J. Chem. Soc., Chem. Commun., 1973, 674 DOI: 10.1039/C39730000674
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