The cis,cis,cis,trans,trans-conformation found for cyclopentasarcosyl in the crystal is also predominant in solution, whereas many other cyclic pentapeptides are conformer mixtures in solution.
K. Titlestad, P. Groth and J. Dale, J. Chem. Soc., Chem. Commun., 1973, 646 DOI: 10.1039/C39730000646
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