The molecular structure of CrO2F2 has been determined in a gas-phase electron diffraction study; the relative magnitudes of the O–Cr–O and F–Cr–F interbond angles are inconsistent with the predictions of V.S.E.P.R. theory, in contrast to the situation in SO2F2.
C. D. Garner, R. Mather and M. F. A. Dove, J. Chem. Soc., Chem. Commun., 1973, 633 DOI: 10.1039/C39730000633
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