On the basis of its calculated electrostatic potential, we suggest that electrophilic attack on furan proceeds through the shifting of a hydrogen out of the molecule plane, producing an approximately tetrahedral carbon.
P. Politzer, R. A. Donnelly and K. C. Daiker, J. Chem. Soc., Chem. Commun., 1973, 617 DOI: 10.1039/C39730000617
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