An antisymbiotic bonding trend has been observed for a series of solutions of linear LAu(thiocyanate) complexes, i.e., in a constant steric environment, irrespective of the solvent used, the Au–NCS/Au–SCN ratio increases as the trans-effect of the L ligand increases.
J. L. Burmeister and J. B. Melpolder, J. Chem. Soc., Chem. Commun., 1973, 613 DOI: 10.1039/C39730000613
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