Direct(>3000 Å) and sensitized photolyses of benzoylmethylene(triphenyl)phosphorane in cyclohexene yielded 1:1·2 and 6·5:1 ratios of acetophenone and 7-norcaryl phenyl ketone, respectively, demonstrating that benzoylcarbene is a primary photoproduct.
R. R. da Silva, V. G. Toscano and R. G. Weiss, J. Chem. Soc., Chem. Commun., 1973, 567 DOI: 10.1039/C39730000567
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