A template effect between furan rings and several metallic cations leads to an improved yield of a 16-membered fheterocyclic ring which does not form any addition complex with salts, while the corresponding saturated gives 1:1 complexes with lithium perchlorate and thiocyanate.
M. Chastette and F. Chastrette, J. Chem. Soc., Chem. Commun., 1973, 534 DOI: 10.1039/C39730000534
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