4-2′-Carboxyphenyl-4-oxobutanoic acid (1), the established precursor of several plant and becterial neapthoquinones, has been found to be also an excellent precursor (13·5% incorporation) of shihunine, a phathalidepyrrolidine alkaloid present in Dendrobium pirardii.
E. Leete and G. B. Bodem, J. Chem. Soc., Chem. Commun., 1973, 522 DOI: 10.1039/C39730000522
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