Alkynes and dienes undergo self-hydrogenation on magnesium and other metal films apparently through an interaction between adsorbed alkynes or dienes and a hydrocarbon residue, probably a polymer, deposited on the metal surface.
Y. Gault, J. Chem. Soc., Chem. Commun., 1973, 478 DOI: 10.1039/C39730000478
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