Issue 13, 1973
From the journal:

Journal of the Chemical Society, Chemical Communications

Structure of [Pd{C5(CO2Me)4(CO2Me)C(CO2Me)Cl}{acac}] and the intermediacy of a σ-butadienyl complex in the PdII-induced trimerisation of dimethyl acetylenedicarboxylate

David M. Roe,   Crispin Calvo,   Narasimham Krishnamachari,   Keith Moseley  and  Peter M. Maitlis  

Abstract

The structure of the complex, [[graphic omitted] C(CO2Me)Cl}Cl]2, obtained from reaction of dimethyl acetylenedicarboxylate (dma) and Pd(PhCN)2Cl2, has been established spectroscopically and confirmed by X-ray analysis of the acetylacetonate; such complexes were also obtained by reaction of a σ-butadienyl complex with dma.

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Article information

DOI
https://doi.org/10.1039/C39730000436
Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 436-438

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Structure of [Pd{C5(CO2Me)4(CO2Me)C(CO2Me)Cl}{acac}] and the intermediacy of a σ-butadienyl complex in the PdII-induced trimerisation of dimethyl acetylenedicarboxylate

D. M. Roe, C. Calvo, N. Krishnamachari, K. Moseley and P. M. Maitlis, J. Chem. Soc., Chem. Commun., 1973, 436 DOI: 10.1039/C39730000436

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