Issue 11, 1973

Photolysis of diazocyclopentadiene in alkyl sulphides. Formation of sulphonium cyclopentadienylides

Abstract

Photolysis of diazocyclopentadiene in the presence of dimethyl, diethy, and tetramethylene sulphides gave the corresponding sulphonium cyclopentadienylide; the ylide from di-t-butyl sulphide was unstable, and the reaction mixture gave the C–H and C–S insertion product from cyclopentadienylidene and the olefin elimination product.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 365-366

Photolysis of diazocyclopentadiene in alkyl sulphides. Formation of sulphonium cyclopentadienylides

W. Ando, J. Suzuki, Y. Saiki and T. Migita, J. Chem. Soc., Chem. Commun., 1973, 365 DOI: 10.1039/C39730000365

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