The nucleophilic reactivities of the anions H–, F–, OH–, and NH2– for substitutions at CH3Cl were determined quantitatively in the gas phase at 300 K using the flowing afterglow technique; comparisons are made with gas-phase basicities and solution nucleophilic reactivities.
L. B. Young, E. Lee-Ruff and D. K. Bohme, J. Chem. Soc., Chem. Commun., 1973, 35b DOI: 10.1039/C3973000035B
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