Issue 9, 1973

Stereoselectivity and adsorption in the Kolbe reaction

Abstract

The distribution of stereoisomeric dimers and ethers, and the dimer: alkene ratio in the products of anodic oxidation of 4-substituted cyclohexane- and cyclo-hexene-carboxylates strongly suggests that for saturated molecules adsorption is unimportant but that for unsaturated carboxylates it can influence the product distribution.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 305-306

Stereoselectivity and adsorption in the Kolbe reaction

G. E. Hawkes, J. H. P. Utley and G. B. Yates, J. Chem. Soc., Chem. Commun., 1973, 305 DOI: 10.1039/C39730000305

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