Activation enthalpies for reactions of several metal-metal bonded carbonyls are shown to correlate well with force constants for the metal-metal vibration, and with energies of a u.v. absorption band tht can be assigned to a σ→σ* transition between orbitals of the metal-metal bond.
J. P. Fawcett, A. J. Poë and M. V. Twigg, J. Chem. Soc., Chem. Commun., 1973, 267 DOI: 10.1039/C39730000267
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