Proton addition to bicyclo[6,1,0]nonatrienetricarbonylmolybdenum (I) gives complex (II) in which a π- to σ-rearrangement has taken place with σ-bonding between Mo and C(2) and π-bonding between Mo and the pentadienyl C(3)–C(7).
M. Brookhart, D. L. Harris and R. C. Dammann, J. Chem. Soc., Chem. Commun., 1973, 187 DOI: 10.1039/C39730000187
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