Issue 5, 1973

Homogeneous catalytic activation of Grignard reagents by nickel complexes. A new stereospecific method for reduction of alkoxy-, chloro-, and fluoro-silanes

Abstract

A highly stereospecific preparative route to R1R2R3Si*H is described involving the reaction between R1R2R3Si*X (X = OMe, F, or Cl) and Grignard reagents possessing β-hydrogens (Et, Prn, Pri, Bun, Bui) activated by a nickel catalyst.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 164-165

Homogeneous catalytic activation of Grignard reagents by nickel complexes. A new stereospecific method for reduction of alkoxy-, chloro-, and fluoro-silanes

R. J. P. Corriu and B. Meunier, J. Chem. Soc., Chem. Commun., 1973, 164 DOI: 10.1039/C39730000164

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