SCHEDULED MAINTENANCE
Nuclear Overhauser experiments indicate that the ring protons of cation (1a) which undergo fast base-catalysed exchange are cis to S–Me; values of Jgem for conformationally rigid thiolanium cations suggest a half-chair conformation for (I).
A. Garbesi, G. Barbarella and A. Fava, J. Chem. Soc., Chem. Commun., 1973, 155 DOI: 10.1039/C39730000155
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