Issue 5, 1973

Preparation of 1-methyl-2,2-diphenylcyclopropylcobaloxime and theoretical considerations for its mode of formation

Abstract

The title compound, which contains a stable tertiary alkylcobalt σ-bond, is readily obtained from the reaction of pyridine[bis(dimethylglyoximato)]cobalt(I) and 1-methyl-2,2-diphenylcyclopyl bromide; five mechanisms for the reactions of low-valent metal ions and alkyl halides are discussed.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 153-154

Preparation of 1-methyl-2,2-diphenylcyclopropylcobaloxime and theoretical considerations for its mode of formation

F. R. Jensen and D. H. Buchanan, J. Chem. Soc., Chem. Commun., 1973, 153 DOI: 10.1039/C39730000153

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