U.v. irradiation of [Fe(CO)3pi;-C4Me4] with C2F3H affords as one of the products an adduct (II) containing a bridging CH(CF3) group; thermolysis of (II) leads to C4 to C5 ring-expansion reactions with the formation of [Fe(CO)2π-C5Me4CF3]2 and a ketonic C5π-allylic complex.
A. Bond, M. Green and S. H. Taylor, J. Chem. Soc., Chem. Commun., 1973, 112 DOI: 10.1039/C39730000112
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