Issue 4, 1973

Evidence for the formation of unscavengeable diradical intermediates in the photolysis of cis- and trans-3-ethyl-2-propylthietan

Abstract

The gas-phase photolysis of either cis-or trans-3-ethyl-2-propylthietan produces but-1-ene, cis- and trans-hept-3-ene, and isomerized substrate, the yields of which are unaffected by adding NO or CO2; a short-lived diradical intermediate is indicated.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 106-107

Evidence for the formation of unscavengeable diradical intermediates in the photolysis of cis- and trans-3-ethyl-2-propylthietan

D. R. Dice and R. P. Steer, J. Chem. Soc., Chem. Commun., 1973, 106 DOI: 10.1039/C39730000106

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