Issue 4, 1973

Ring contraction of 2-alkylidenecyclobutanols to cyclopropyl carbonyl compounds

Abstract

2-Alkylidenecyclobutanols when heated in a sealed tube or in 5% H2SO4 undergo ring contraction to 1-alkylcyclopropyl carbonyl compounds; subsequent rearrangement into homoallylic carbonyl derivatives occurs when 1,5 hydrogen transfer is possible.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 103-104

Ring contraction of 2-alkylidenecyclobutanols to cyclopropyl carbonyl compounds

J. P. Barnier, J. M. Denis, J. R. Salaün and J. M. Conia, J. Chem. Soc., Chem. Commun., 1973, 103 DOI: 10.1039/C39730000103

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements