The XeOF5+ ion (prepared with KrF+ as oxidizer) is related to XeOF3+; the latter is in turn related to XeF3+, the geometry of which has been established by X-ray crystallography.
D. E. McKee, C. J. Adams, A. Zalkin and N. Bartlett, J. Chem. Soc., Chem. Commun., 1973, 26 DOI: 10.1039/C39730000026
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