Interaction of Me3SiCH2Li with CuI gives (Me3SiCH2Cu)na stable, volatile, petroleum-solublecopper-(I) alkyl (tetramer in C6H6, hexamer in n-C6H14), which shows a parent ion in the mass spectrum corresponding to the tetramer (n= 4); decomposition involves free radical pathways.
M. F. Lappert and R. Pearce, J. Chem. Soc., Chem. Commun., 1973, 24 DOI: 10.1039/C39730000024
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