Issue 11, 1972

Crystal structure of bis-p-nitrophenylcarbodi-imide, O2N·C6H4·N:C:N·C6H4·NO2

Abstract

Crystals of the title compound (I) are orthorhombic with a= 24·738, b= 3·827, c= 13·277 Å, Z= 4, space group Pna21. The structure was solved by direct methods. 1205 Visually estimated X-ray intensities were refined by full-matrix least-squares to R 7·73%. The molecule differs markedly from an idealised allene type. Important differences (idealised values in parentheses) are: C–N[double bond, length half m-dash]C 129·6 and 134·4°(120°), N[double bond, length half m-dash]C[double bond, length half m-dash]N 169·7°(180°), and C–N ⋯ N–C torsion angle 113·5°(90°).

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1972, 1567-1571

Crystal structure of bis-p-nitrophenylcarbodi-imide, O2N·C6H4·N:C:N·C6H4·NO2

A. T. Vincent and P. J. Wheatley, J. Chem. Soc., Perkin Trans. 2, 1972, 1567 DOI: 10.1039/P29720001567

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements