Rearrangement of [2-2H]isobutyl phenyl ether with aluminium bromide in chlorobenzene leads to a mixture of s-butylphenols and chloro-s-butylbenzenes in which deuterium has been scrambled between the 2- and 3-positions. This result supports a recent conclusion that such rearrangements do not involve π-complex intermediates but are of carbonium ion type.
M. J. S. Dewar and P. A. Spanninger, J. Chem. Soc., Perkin Trans. 2, 1972, 1204 DOI: 10.1039/P29720001204
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...