Issue 8, 1972

Pyrolysis of carbonates. Part I. The gas-phase pyrolysis of some symmetrical primary alkyl carbonates

Abstract

The effect of structure on the rate of pyrolysis is similar for acetates and carbonates. The rates for carbonates are ca. 24 times greater than those for acetates. This increase derives about equally from the lower activation energies and more positive entropies of activation. The reasons for this are discussed.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1972, 926-928

Pyrolysis of carbonates. Part I. The gas-phase pyrolysis of some symmetrical primary alkyl carbonates

D. B. Bigley and C. M. Wren, J. Chem. Soc., Perkin Trans. 2, 1972, 926 DOI: 10.1039/P29720000926

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