Epoxidation of trichodermol and some derivatives gave the 9β, 10β-epoxide although osmylation appeared to give the 9α, 10α-glycol. Reduction of trichodermone with sodium borohydride gave 4-epitrichodermol. Elimination of the 4-hydroxy-group with phosphorus pentachloride afforded the Δ3-olefin without rearrangement.
P. M. Adams and J. R. Hanson, J. Chem. Soc., Perkin Trans. 1, 1972, 2283 DOI: 10.1039/P19720002283
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...