Diethyl ketone, hexafluoroacetone, and hexachloroacetone have been fluorinated over potassium tetrafluoro-cobaltate(III) to give polyfluoroacyl fluorides as the major products. Diethyl ketone was completely cleaved by cobalt(III) fluoride, though heptafluoro-n-propyl methyl ketone gave heptafluorobutyryl fluoride.
R. D. Bagnall, P. L. Coe and J. C. Tatlow, J. Chem. Soc., Perkin Trans. 1, 1972, 2277 DOI: 10.1039/P19720002277
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