4-Methyloestra-1,3,5(10)-trien-17-one and small amounts of androst-4-ene-6,17-dione and a 17-oxoanthrasteroid are formed when 3-substituted 5α,6α-epoxyandrostan-17-ones are treated with hydrobromic acid in glacial acetic acid.
A. G. Ogilvie and J. R. Hanson, J. Chem. Soc., Perkin Trans. 1, 1972, 1981 DOI: 10.1039/P19720001981
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