Bromination of some α-ketols resulted in cleavage of the carbonyl–carbinol bond; 1-hydroxy-1,1 -diphenylacetone, for example, gave benzophenone. Bromination of diphenyl-substituted tertiary alcohols does not cause degradation and the products are bromohydrins and/or substituted alkenes.
J. A. Donnelly and R. O'Donnell, J. Chem. Soc., Perkin Trans. 1, 1972, 1875 DOI: 10.1039/P19720001875
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